CBSE Notes, Lectures

CBSE - Chemistry - Metals and Non-metals

Metals and Non-metals

Long Answer Type

Give the steps involved in the extraction of metals of low and medium reactivity from their respective sulphide ores.

During extraction of metals of low and medium reactivity, a respective sulphide ore is first heated in air. This helps in obtaining oxide of metal. It is easier to extract a metal from its oxide rather than from its sulphide. Hence, this step is used. Mercury is a metal of low reactivity. Mercury sulphide (cinnabar) is heated in air. Mercury sulphide gets oxidized to produce mercury oxide. 

2HgS +3O2 → 2HgO + 2SO2
After that, mercury oxide is reduced to obtain mercury. 
2HgO → 2Hg + O2

Zinc is a metal of medium reactivity. It is found as zinc blende (ZnS).
 Zinc blende is roasted to obtain zinc oxide. After that, zinc oxide is reduced to obtain pure zinc. 

2ZnS + 3O2 → ZnO + 2SO2

After that, mercury oxide is reduced to obtain mercury.
ZnO + C → Zn + CO 

.